Semiconductor
A semiconductor is a solid material that has electrical conductivity in between that of an conductor and that of an insulator; it can vary over that wide range either permanently or dynamically. Semiconductors are tremendously important in technology. Semiconductor devices, electronic components made of semiconductor materials, are essential in modern electrical devices. Examples range from computers to cellular phones to digital audio players. Silicon is used to create most semiconductors commercially, but dozens of other materials are used as well.Overview
Semiconductors are very similar to insulators. The two categories of solids differ primarily in that insulators have larger band gaps — energies that electrons must acquire to be free to move from atom to atom. In semiconductors at room temperature, just as in insulators, very few electrons gain enough thermal energy to leap the band gap from the valence band to the conduction band, which is necessary for electrons to be available for electric current conduction. For this reason, pure semiconductors and insulators in the absence of applied electric fields, have roughly similar resistance. The smaller bandgaps of semiconductors, however, allow for other means besides temperature to control their electrical properties.
Semiconductors' intrinsic electrical properties are often permanently modified by introducing impurities by a process known as doping. Usually, it is sufficient to approximate that each impurity atom adds one electron or one "hole" (a concept to be discussed later) that may flow freely. Upon the addition of a sufficiently large proportion of impurity dopants, semiconductors will conduct electricity nearly as well as metals. Depending on the kind of impurity, a doped region of semiconductor can have more electrons or holes, and is named N-type or P-type semiconductor material, respectively. Junctions between regions of N- and P-type semiconductors create electric fields, which cause electrons and holes to be available to move away from them, and this effect is critical to semiconductor device operation. Also, a density difference in the amount of impurities produces a small electric field in the region which is used to accelerate non-equilibrium electrons or holes.
In addition to permanent modification through doping, the resistance of semiconductors is normally modified dynamically by applying electric fields. The ability to control resistance/conductivity in regions of semiconductor material dynamically through the application of electric fields is the feature that makes semiconductors useful. It has led to the development of a broad range of semiconductor devices, like transistors and diodes. Semiconductor devices that have dynamically controllable conductivity, such as transistors, are the building blocks of integrated circuits devices like the microprocessor. These "active" semiconductor devices (transistors) are combined with passive components implemented from semiconductor material such as capacitors and resistors, to produce complete electronic circuits.
In most semiconductors, when electrons lose enough energy to fall from the conduction band to the valence band (the energy levels above and below the band gap), they often emit light, a quantum of energy in the visible electromagnetic spectrum. This photoemission process underlies the light-emitting diode (LED) and the semiconductor laser, both of which are very important commercially. Conversely, semiconductor absorption of light in photodetectors excites electrons to move from the valence band to the higher energy conduction band, thus facilitating detection of light and vary with its intensity. This is useful for fiber optic communications, and providing the basis for energy from solar cells.
Semiconductors may be elemental materials such as silicon and germanium, or compound semiconductors such as gallium arsenide and indium phosphide, or alloys such as silicon germanium or aluminium gallium arsenide.
Doping
In semiconductor production, doping refers to the process of intentionally introducing impurities into an extremely pure (also referred to as intrinsic) semiconductor in order to change its electrical properties. The impurities are dependent upon the type of semiconductor. Lightly and moderately doped semiconductors are referred to as extrinsic. A semiconductor which is doped to such high levels that it acts more like a conductor than a semiconductor is called degenerate.
Some dopants are generally added as the (usually silicon) boule is grown, giving each wafer an almost uniform initial doping. To define circuit elements, selected areas (typically controlled by photolithography)are further doped by such processes as diffusion[2] and ion implantation, the latter method being more popular in large production runs due to its better controllability.
The number of dopant atoms needed to create a difference in the ability of a semiconductor to conduct is very small. Where a comparatively small number of dopant atoms are added (of the order of 1 every 100,000,000 atoms) then the doping is said to be low, or light. Where many more are added (of the order of 1 in 10,000) then the doping is referred to as heavy, or high. This is often shown as n+ for n-type dopant or p+ for p-type doping.
Dopants
The materials chosen as suitable dopants depend on the atomic properties of both the dopant and the material to be doped. In general, dopants that produce the desired controlled changes are classified as either electron acceptors or donors. A donor atom that activates (that is, becomes incorporated into the crystal lattice) donates weakly-bound valence electrons to the material, creating excess negative charge carriers. These weakly-bound electrons can move about in the crystal lattice relatively freely and can facilitate conduction in the presence of an electric field. (The donor atoms introduce some states under, but very close to the conduction band edge. Electrons at these states can be easily excited to conduction band, becoming free electrons, at room temperature.) Conversely, an activated acceptor produces a hole. Semiconductors doped with donor impurities are called n-type, while those doped with acceptor impurities are known as p-type. The n and p type designations indicate which charge carrier acts as the material's majority carrier. The opposite carrier is called the minority carrier, which exists due to thermal excitation at a much lower concentration compared to the majority carrier.
For example, the pure semiconductor silicon has four valence electrons. In silicon, the most common dopants are IUPAC group 13 (commonly known as group III) and group 15 (commonly known as group V) elements. Group 13 elements all contain three valence electrons, causing them to function as acceptors when used to dope silicon. Group 15 elements have five valence electrons, which allows them to act as a donor. Therefore, a silicon crystal doped with boron creates a p-type semiconductor whereas one doped with phosphorus results in an n-type material.
p-n junction
is formed by combining P-type and N-type semiconductors together in very close contact. Normally they are manufactured from a single crystal with different dopant concentrations diffused across it. Creating a semiconductor from two separate pieces of material introduces a grain boundary between them which would severely inhibit its utility by scattering the electrons and holes. The term junction refers to the region where the two regions of the semiconductor meet. It can be thought of as the border region between the P-type and N-type blocks as shown in the following diagram:The p-n junction possesses some interesting properties which have useful applications in modern electronics. P-doped semiconductor is relatively conductive. The same is true of N-doped semiconductor, but the junction between them is a nonconductor. This nonconducting layer, called the depletion zone, occurs because the electrical charge carriers in doped n-type and p-type silicon (electrons and holes, respectively) attract and eliminate each other in a process called recombination. By manipulating this nonconductive layer, p-n junctions are commonly used as diodes: electrical switches that allow a flow of electricity in one direction but not in the other (opposite) direction. This property is explained in terms of the forward-bias and reverse-bias effects, where the term bias refers to an application of electric voltage to the p-n junction.
A common type of transistor, the bipolar junction transistor, consists of two p-n junctions in series, for example in the form n-p-n; no current can flow through it unless a separate small voltage is applied to the middle layer. The most common type of solar cell is basically a large p-n junction; the free carrier pairs created by light energy are separated by the junction and contribute to current.
The invention of the p-n junction is usually attributed to Russell Ohl, Bell Laboratories.
1. Forward-bias
Forward-bias occurs when the P-type semiconductor material is connected to the positive terminal of a battery and the N-type semiconductor material is connected to the negativeterminal, as shown below.
With a battery connected this way, the holes in the P-type region and the electrons in the N-type region are pushed towards the junction. This reduces the width of the depletion zone. The positive charge applied to the P-type material repels the holes, while the negative charge applied to the N-type material repels the electrons. As electrons and holes are pushed towards the junction, the distance between them decreases. This lowers the barrier in potential. With increasing forward-bias voltage, the depletion zone eventually becomes thin enough that the zone's electric field can't counteract majority charge carrier motion (physics) across the p-n junction, consequently reducing electrical resistance. The electrons (or holes) which cross the p-n junction into the P-type material (or into the N-type material for holes) will diffuse in the near-neutral region. Therefore, the amount of minority diffusion in the near-neutral zones determines the amount of current that may flow through the diode.
Electrons flow through the circuit from the negative battery terminal to the positive terminal of the battery. They are emitted at the negative battery terminal, then move through the connection wire into the N-type material at which point they move towards the p-n junction. When the p-n junction electric barrier no longer keeps electrons contained in the N-type material (because the thin depletion zone produces little electrical resistance against the flow of electrons), the electrons cross the p-n junction moving into the P-type material. Once in the P-type material, the electrons, being thermally free (from bonding, i.e. mobile) will move through the rest of the P-type material and back to the positive terminal of the battery. Note that the electron does not jump from one hole to the next in the p-type material, that would entail an electron-hole recombination which immobilizes both hole and electron. Instead, the electrons move freely through the P-type material without needing to jump into (i.e. recombine with) holes. This process occurs for all electrons arriving at the N-type material, thus allowing an electrical current to flow through the circuit path that includes the p-n junction.
The Shockley diode equation models the forward-bias operational characteristics of a p-n junction outside the avalanche (foward-biased conducting) region.
2. Reverse-bias
Connecting the P-type region to the negative terminal of the battery and the N-type region to the positive terminal, produces the reverse-bias effect. The connections are illustrated in the following diagram:
Because the P-type material is now connected to the negative terminal of the power supply, the 'holes' in the P-type material are pulled away from the junction, causing the width of the depletion zone to increase. Similarly, because the N-type region is connected to the positive terminal, the electrons will also be pulled away from the junction. Therefore the depletion region widens, and does so increasingly with increasing reverse-bias voltage. This increases the voltage barrier causing a high resistance to the flow of charge carriers thus allowing minimal electric current to cross the p-n junction.
The strength of the depletion zone electric field increases as the reverse-bias voltage increases. Once the electric field intensity increases beyond a critical level, the p-n junction depletion zone breaks-down and current begins to flow, usually by either the Zener or avalanche breakdown processes. Both of these breakdown processes are non-destructive and are reversible, so long as the amount of current flowing does not reach levels that cause the semiconductor material to overheat and cause thermal damage.
Semiconductor diodesMost modern diodes are based on semiconductor p-n junctions. In a p-n diode, conventional current can flow from the p-type side (the anode) to the n-type side (the cathode), but cannot flow in the opposite direction. Another type of semiconductor diode, the Schottky diode, is formed from the contact between a metal and a semiconductor rather than by a p-n junction.
Voltage-Current characteristics
A semiconductor diode’s voltage-current, or V-I, characteristic curve is related to the transport of carriers through the so-called depletion layer or depletion region that exists at the p-n junction between differing semiconductors. When a p-n junction is first created, conduction band (mobile) electrons from the N-doped region diffuse into the P-doped region where there is a large population of holes (places for electrons in which no electron is present) with which the electrons “recombine”. When a mobile electron recombines with a hole, both hole and electron vanish, leaving behind an immobile positively charged donor on the N-side and negatively charged acceptor on the P-side. The region around the p-n junction becomes depleted of charge carriers and thus behaves as an insulator.
However, the depletion width cannot grow without limit. For each electron-hole pair that recombines, a positively-charged dopant ion is left behind in the N-doped region, and a negatively charged dopant ion is left behind in the P-doped region. As recombination proceeds and more ions are created, an increasing electric field develops through the depletion zone which acts to slow and then finally stop recombination. At this point, there is a “built-in” potential across the depletion zone.
If an external voltage is placed across the diode with the same polarity as the built-in potential, the depletion zone continues to act as an insulator preventing a significant electric current. This is the reverse bias phenomenon. However, if the polarity of the external voltage opposes the built-in potential, recombination can once again proceed resulting in substantial electric current through the p-n junction. For silicon diodes, the built-in potential is approximately 0.6 V. Thus, if an external current is passed through the diode, about 0.6 V will be developed across the diode such that the P-doped region is positive with respect to the N-doped region and the diode is said to be “turned on” as it has a forward bias.
A diode’s I–V characteristic can be approximated by four regions of operation (see the figure at right).
At very large reverse bias, beyond the peak inverse voltage or PIV, a process called reverse breakdown occurs which causes a large increase in current that usually damages the device permanently. The avalanche diode is deliberately designed for use in the avalanche region. In the Zener diode, the concept of PIV is not applicable. A Zener diode contains a heavily doped p-n junction allowing electrons to tunnel from the valence band of the p-type material to the conduction band of the n-type material, such that the reverse voltage is “clamped” to a known value (called the Zener voltage), and avalanche does not occur. Both devices, however, do have a limit to the maximum current and power in the clamped reverse voltage region.
The second region, at reverse biases more positive than the PIV, only a very small reverse saturation current flows. In the reverse bias region for a normal P-N rectifier diode, the current through the device is very low (in the µA range).
The third region is forward but small bias, where only a small forward current is conducted.
As the potential difference is increased above an arbitrarily defined cut-in voltage or on-voltage, the diode current becomes appreciable (the level of current considered “appreciable” and the value of cut-in voltage depends on the application), and the diode presents a very low resistance.
The current–voltage curve is exponential. In a normal silicon diode at rated currents, the arbitrary 'cut-in' voltage is defined as 0.6 to 0.7 volts. The value is different for other diode types — Schottky diodes can be as low as 0.2 V and red light-emitting diodes (LEDs) can be 1.4 V or more and blue LEDs can be up to 4.0 V.
At higher currents the forward voltage drop of the diode increases. A drop of 1v to 1.5v is typical at full rated current for power diodes.
Shockley diode equation
The Shockley ideal diode equation or the diode law (named after transistor co-inventor William Bradford Shockley, not to be confused with tetrode inventor Walter H. Schottky) is the I–V characteristic of an ideal diode in either forward or reverse bias (or no bias). It is derived with the assumption that the only processes giving rise to current in the diode are drift (due to electrical field), diffusion, and thermal recombination-generation. It also assumes that the recombination-generation (R-G) current in the depletion region is insignificant. This means that the Shockley equation doesn’t account for the processes involved in reverse breakdown and photon-assisted R-G. Additionally, it doesn’t describe the “leveling off” of the I–V curve at high forward bias due to internal resistance, nor does it explain the practical deviation from the ideal at very low forward bias due to R-G current in the depletion region.where
- I is the diode current,
- IS is a scale factor called the saturation current,
- VD is the voltage across the diode,
- VT is the thermal voltage,
- and n is the emission coefficient, also known as the ideality factor.
The thermal voltage VT is approximately 25.85 mV at 300 K, a temperature close to “room temperature” commonly used in device simulation software. At any temperature it is a known constant defined by:
where
- q is the magnitude of charge on an electron (the elementary charge),
- k is Boltzmann’s constant,
- T is the absolute temperature of the p-n junction in kelvins
For even rather small voltages the exponential is very large because the thermal voltage is very small, so the subtracted ‘1’ in the diode equation is negligible and the diode current is often approximated as
The emission coefficient n varies from about 1 to 2 depending on the fabrication process and semiconductor material and in many cases is assumed to be approximately equal to 1 (thus the notation n is omitted).
Types of semiconductor diodes
There are several types of junction diodes, which either emphasizes a different physical aspects of a diode often by geometric scaling, doping level, choosing the right electrodes, are just an application of a diode in a special circuit, or are really different devices like the Gunn and laser diode and the JFET:
- Normal (p-n) diodes
- which operate as described above. Usually made of doped silicon or, more rarely, germanium. Before the development of modern silicon power rectifier diodes, cuprous oxide and later selenium was used; its low efficiency gave it a much higher forward voltage drop (typically 1.4–1.7 V per “cell”, with multiple cells stacked to increase the peak inverse voltage rating in high voltage rectifiers), and required a large heat sink (often an extension of the diode’s metal substrate), much larger than a silicon diode of the same current ratings would require. The vast majority of all diodes are the p-n diodes found in CMOS integrated circuits, which include 2 diodes per pin and many other internal diodes.
- Switching diodes
- Switching diodes, sometimes also called small signal diodes, are a single p-n diode in a discrete package. A switching diode provides essentially the same function as a switch. Below the specified applied voltage it has high resistance similar to an open switch, while above that voltage it suddenly changes to the low resistance of a closed switch. They are used in devices such as ring modulation.
- Schottky diodes
- Schottky diodes are constructed from a metal to semiconductor contact. They have a lower forward voltage drop than any p-n junction diode. Their forward voltage drop at forward currents of about 1 mA is in the range 0.15 V to 0.45 V, which makes them useful in voltage clamping applications and prevention of transistor saturation. They can also be used as low loss rectifiers although their reverse leakage current is generally much higher than non Schottky rectifiers. Schottky diodes are majority carrier devices and so do not suffer from minority carrier storage problems that slow down most normal diodes — so they have a faster “reverse recovery” than any p-n junction diode. They also tend to have much lower junction capacitance than PN diodes and this contributes towards their high switching speed and their suitability in high speed circuits and RF devices such as switched-mode power supply, mixers and detectors.
- Super Barrier Diodes
- Super barrier diodes are rectifier diodes that incorporate the low forward voltage drop of the Schottky diode with the surge-handling capability and low reverse leakage current of a normal p-n junction diode.
- “Gold-doped” diodes
- As a dopant, gold (or platinum) acts as recombination centers, which help a fast recombination of minority carriers. This allows the diode to operate at signal frequencies, at the expense of a higher forward voltage drop. Gold doped diodes are faster than other p-n diodes (but not as fast as Schottky diodes). They also have less reverse-current leakage than Schottky diodes (but not as good as other p-n diodes).A typical example is the 1N914.
- Snap-off or Step recovery diodes
- The term ‘step recovery’ relates to the form of the reverse recovery characteristic of these devices. After a forward current has been passing in an SRD and the current is interrupted or reversed, the reverse conduction will cease very abruptly (as in a step waveform). SRDs can therefore provide very fast voltage transitions by the very sudden disappearance of the charge carriers.
- Point-contact diodes
- These work the same as the junction semiconductor diodes described above, but their construction is simpler. A block of n-type semiconductor is built, and a conducting sharp-point contact made with some group-3 metal is placed in contact with the semiconductor. Some metal migrates into the semiconductor to make a small region of p-type semiconductor near the contact. The long-popular 1N34 germanium version is still used in radio receivers as a detector and occasionally in specialized analog electronics.
- Cat’s whisker or crystal diodes
- These are a type of point contact diode. The cat’s whisker diode consists of a thin or sharpened metal wire pressed against a semiconducting crystal, typically galena or a piece of coal.The wire forms the anode and the crystal forms the cathode. Cat’s whisker diodes were also called crystal diodes and found application in crystal radio receivers. Cat’s whisker diodes are obsolete.
- PIN diodes
- A PIN diode has a central un-doped, or intrinsic, layer, forming a p-type / intrinsic / n-type structure. They are used as radio frequency switches and attenuators. They are also used as large volume ionizing radiation detectors and as photodetectors. PIN diodes are also used in power electronics, as their central layer can withstand high voltages. Furthermore, the PIN structure can be found in many power semiconductor devices, such as IGBTs, power MOSFETs, and thyristors.
- Varicap or varactor diodes
- These are used as voltage-controlled capacitors. These are important in PLL (phase-locked loop) and FLL (frequency-locked loop) circuits, allowing tuning circuits, such as those in television receivers, to lock quickly, replacing older designs that took a long time to warm up and lock. A PLL is faster than a FLL, but prone to integer harmonic locking (if one attempts to lock to a broadband signal). They also enabled tunable oscillators in early discrete tuning of radios, where a cheap and stable, but fixed-frequency, crystal oscillator provided the reference frequency for a voltage-controlled oscillator.
- Zener diodes
- Diodes that can be made to conduct backwards. This effect, called Zener breakdown, occurs at a precisely defined voltage, allowing the diode to be used as a precision voltage reference. In practical voltage reference circuits Zener and switching diodes are connected in series and opposite directions to balance the temperature coefficient to near zero. Some devices labeled as high-voltage Zener diodes are actually avalanche diodes (see below). Two (equivalent) Zeners in series and in reverse order, in the same package, constitute a transient absorber (or Transorb, a registered trademark). They are named for Dr. Clarence Melvin Zener of Southern Illinois University, inventor of the device.
- Avalanche diodes
- Diodes that conduct in the reverse direction when the reverse bias voltage exceeds the breakdown voltage. These are electrically very similar to Zener diodes, and are often mistakenly called Zener diodes, but break down by a different mechanism, the avalanche effect. This occurs when the reverse electric field across the p-n junction causes a wave of ionization, reminiscent of an avalanche, leading to a large current. Avalanche diodes are designed to break down at a well-defined reverse voltage without being destroyed. The difference between the avalanche diode (which has a reverse breakdown above about 6.2 V) and the Zener is that the channel length of the former exceeds the “mean free path” of the electrons, so there are collisions between them on the way out. The only practical difference is that the two types have temperature coefficients of opposite polarities.
- Transient voltage suppression diode (TVS)
- These are avalanche diodes designed specifically to protect other semiconductor devices from high-voltage transients. Their p-n junctions have a much larger cross-sectional area than those of a normal diode, allowing them to conduct large currents to ground without sustaining damage.
- Photodiodes
- All semiconductors are subject to optical charge carrier generation. This is typically an undesired effect, so most semiconductors are packaged in light blocking material. Photodiodes are intended to sense light(photodetector), so they are packaged in materials that allow light to pass, and are usually PIN (the kind of diode most sensitive to light). A photodiode can be used in solar cells, in photometry, or in optical communications. Multiple photodiodes may be packaged in a single device, either as a linear array or as a two dimensional array. These arrays should not be confused with charge-coupled devices.
- Light-emitting diodes (LEDs)
- In a diode formed from a direct band-gap semiconductor, such as gallium arsenide, carriers that cross the junction emit photons when they recombine with the majority carrier on the other side. Depending on the material, wavelengths (or colors) from the infrared to the near ultraviolet may be produced. The forward potential of these diodes depends on the wavelength of the emitted photons: 1.2 V corresponds to red, 2.4 to violet. The first LEDs were red and yellow, and higher-frequency diodes have been developed over time. All LEDs are monochromatic; “white” LEDs are actually combinations of three LEDs of a different color, or a blue LED with a yellow scintillator coating. LEDs can also be used as low-efficiency photodiodes in signal applications. An LED may be paired with a photodiode or phototransistor in the same package, to form an opto-isolator.
- Laser diodes
- When an LED-like structure is contained in a resonant cavity formed by polishing the parallel end faces, a laser can be formed. Laser diodes are commonly used in optical storage devices and for high speed optical communication.
- Esaki or tunnel diodes
- these have a region of operation showing negative resistance caused by quantum tunneling, thus allowing amplification of signals and very simple bistable circuits. These diodes are also the type most resistant to nuclear radiation.
- Gunn diodes
- These are similar to tunnel diodes in that they are made of materials such as GaAs or InP that exhibit a region of negative differential resistance. With appropriate biasing, dipole domains form and travel across the diode, allowing high frequency microwave oscillators to be built.
- Peltier diodes
- are used as sensors, heat engines for thermoelectric cooling. Charge carriers absorb and emit their band gap energies as heat.
- Current-limiting field-effect diodes
- These are actually a JFET with the gate shorted to the source, and function like a two-terminal current-limiting analog to the Zener diode; they allow a current through them to rise to a certain value, and then level off at a specific value. Also called CLDs, constant-current diodes, diode-connected transistors, or current-regulating diodes
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